According to sources, producers are said to be very keen on the luscious-lipped actress to play the part of a Russian double agent in Casino Royale.
Should the rumours be true, it will not be the first time Jolie has starred opposite the new James Bond, Daniel Craig.
Craig played Jolie’s love interest in Tomb Raider, and Brad Pitt, who she may or may not be dating, had better be wary of the blonde 007 after their first on-screen pairing, Jolie described Craig as "one of the best kissers" she’d ever met. Jolie’s well-marketed image of sexiness combined with edginess, she married Johnny Lee Miller in 1996 with his name written in blood on her back, would make her an obvious choice to be a dangerous Bond girl.
A source was quoted in The Sun as saying: "Angelina is simply perfect for the part of the ultimate Bond girl." Should Jolie be up for the part, it will be bad news for the other Bond-girl wannabes, who include Jessica Alba, Uma Thurman and ex-S Clubber Rachel Stevens.
Meanwhile it has been reported that Brad Pitt’s family wants him to cool of his relationship with Angelina Jolie, because they still love his ex- wife – Jennifer Aniston.
The family is also worried because Angelina has been divorced twice. Brad’s grandmother, Betty Russell, was quoted as saying: “ The family wants Brad to go slow. Angelina has been married twice, Brad is just divorced”.